The solicitations and topics listed on this site are copies from the various sbir agency solicitations and are not necessarily. Hydrotest water specification and integrity considerations. Sim 05200218 stress corrosion cracking of stainless. The residual stresses from the welded brackets, supports and nozzles and the hot humid environment combined with the chloride levels of the insulation provided the necessary conditions for chloride induced stress corrosion cracking to occur. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Chloride stress corrosion cracking inspectioneering.
The detection and meaningful monitoring of pitting corrosion usually represents a major challenge. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353k with relative humidity rh of 35%. The detection and meaningful monitoring of pitting corrosion usually represents a. Chlorides simulating sea salt particles were put on the gage section of the ss as droplets of synthetic sea water. To that end, types 304, 304l, and 316l stainless steel ubend samples were fabricated and placed in an environmental chamber. In situ synchrotron xray tomography of 304 stainless. Stress corrosion cracking scc microbially induced corrosion mic potable water, such as ph, dissolved oxygen and hardness, are unlikely to cause corrosion problems for stainless steel. Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel.
The drip procedure from the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to nuclear regulatory commission. The effect of salt loading on chlorideinduced stress. The standard 304 304l and 316316l grades are most susceptible. Chlorideinduced transgranular stress corrosion cracking. Samples were subject to 60 mpa stress, 90 c at 70% relative humidity, for 480 h. Stress corrosion of type 304 stainless steel in chloride.
Soilside chloride induced stress corrosion cracking under insulation a length of tp 304 stainless steel pipe in service as a high pressure steam condensate return in an outdoor underground environment beneath a sidewalk along a roadway suffered cracking near its welded ends, while the main body showed no visual signs of failure. Mechanism of chloride stress corrosion cracking of austenitic. On the stress corrosion cracking and hydrogen embrittlement. It has excellent drawdown workability and holds a better strength at higher temperatures than the 304 grade. If you are using stainless steel bolts under tensile stress, in an environment where chlorine corrosion is likely, you should examine the potential for stress corrosion cracking carefully. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Effects of fluoride and other halogen ions on the external. It is my understanding that the presents of any halogen cl, f, br, etc. Chlorideinduced stresscorrosion cracking scc is one of the failure modes of stainless steels. Understanding the risk of chloride induced stress corrosion cracking of interim. This phenomenon is associated with a combination of stress applied or residual above the threshold value2. Performance of nickel and high nickel alloys in chloride media. Initiation strain for chlorideinduced stress corrosion. What is temperature it is more important than concentration of chloride and anything higher than room temperature higher is worse.
The tower provided a caustic solution naoh to remove hcl from the stream, before the latter was directed to a burner. Can normal levels of chlorine in potable city water cause scc in 304 or 316 stainless steels. Three material conditions were used in this evaluation. Transgranular stress corrosion cracking of 304l stainless. Type 304 alloys are all modications of the 18% chromium, 8% nickel austenitic alloy. Stress corrosion cracking scc or environmentally induced cracking could occur at any. Selection of stainless steels for handling chlorine. Fracture mechanicsbased testing was used to quantify the stresscorrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in. Chloride induced stress corrosion cracking of type 304 and 304l stainless steels in air masami mayuzumi, taku arai and koichiro hide.
Chlorideinduced stress corrosion cracking of 316 stainless. Stress corrosion cracking scc or environmentally induced cracking could occur at any electrochemical potential range. It is generally not well understood, and can, given the right conditions, cause catastrophic failure. Chloride stress corrosion cracking in austenitic stainless steel. To that end, simulated sea salt in quantities between 0. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. This paper described the mechanism of chloride induced stress corrosion cracking of oil tube as a result of improper material selection and lack of maintenance. Stress corrosion cracking scc is a phenomenon experienced from time to time in stainless steels. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. Localized corrosion such as pitting and crevice corrosion generally occurs under oxidizing conditions. High residual or applied stress, temperature above 6571c 150160f and chlorides increase the likelihood of cscc. Testing laboratory testing can be carried out according to nace tm0177 5% nacl and 0. Increasing nickel content above 18 to 20% or the use of duplex, or ferritic stainless steels improves resistance to cscc.
These alloys can however suffer from caustic stress corrosion cracking at caustic concentrations above 70% at temperatures above 290crmo c 550f. The stress corrossion behavior of aisi type 304 stainless steel was investigated as a function of the environmental variables, temperature, ph, cation species, and chloride concentration in concentrated solutions of mgcl 2, cacl 2 and licl the time to failure at a constant stress, chloride ion concentration, and temperature increased in the order mgcl 2, cacl 2, licl. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. Highly alloyed austenitic stainless steels s32654, s31254, and n08028, and duplex grades s32750 and s31803 possess much improved resistance to scc compared with s30400 and s31600 steels. Methods of minimizing chloride stress corrosion cracking. The roof was supported by stainless steel rods in tension, which failed due to stress corrosion cracking. In situ synchrotron xray tomography of 304 stainless steels. Stainless steel 304 and ss 316 are attacked by chloride induced stress corrosion cracking lower the dewpoint and while shutdown, unless the complete caution is followed to confirm a bone dry supply to the system and to sustain shutdown and initialization precautions of gas blanketing and maintaining the dryness of system. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Swimming pool roof collapse in 1985, 12 people were killed in uster, switzerland when the concrete roof of a swimming pool collapsed only after thirteen years of use. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Chlorine in contact with water and as a dissolved gas, sometimes found in water treatment applications, is potentially aggressive to stainless steels. The minute discusses the background, noting the effects of chlorine based water distinfection systems and the chloramines generated by body fluid excretions on stainless steel components under applied or residual tensile stress. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small.
In all cases of failure by stress corrosion cracking, the following three factors must be present. Austenitic stainless steel may be susceptible to chloride stress corrosion cracking cscc. Selection of stainless steels for handling chlorine cl2. Chlorine and chloride are different forms of the same element but with vastly different effects on stainless steel. Pdf chloride induced stress corrosion cracking of type 304. Stress corrosion cracking facts and how to reduce the risk. The standard 304304l and 316316l grades are most susceptible. The steel rods had been pitted, causing the roof to cave in. The amount of chlorine contamination for prevention of. Stress corrosion induced failure of 316l stainless steel pipe. The chloride stresscorrosion cracking behavior of stainless. Chloride induced stress corrosion cracking of stainless. Alloy 400 n04400 and alloy 600 n06600 also have excellent stress corrosion resistance.
Chloride induced stress corrosion cracking of type 304. The objective of this work is to evaluate if atmospheric stress corrosion cracking can develop in stainless steel cask. The tomography scans showed the crack morphology evolving into a branching crack around the surface of the sample. C are not recommended for 304 or 316 as they are at risk of sudden failure from chloride stress corrosion cracking. Stress corrosion cracking facts and how to reduce the. Chloride stress corrosion cracking clscc is one of the most common reasons. Like its 304 grade counterpart, 316 stainless steel is nonmagnetic and will not harden under heat treatment. Chlorine is bleach and stainless steels can only tolerate exposure to a few ppm. Chloride is the most important single source of scc. The interaction of corrosion fatigue and stresscorrosion. Stress corrosion cracking of sensitized type 304 stainless.
Both of type 304 and type 316 stainless steels showed quite similar. Grades with high resistance to chlorideinduced stress corrosion cracking scc. Atmospheric salt fog testing to evaluate chloride induced. The amount of chlorine contamination for prevention of stress corrosion cracking in sensitized type 304 stainless steel moriyasu tokiwai, hideo kimura and hideo kusanagi central research institute of electric power industry, energy. Stress corrosion cracking of austenitic stainless steel 304l. Industrial experience on the caustic cracking of stainless. Transgranular stress corrosion cracking of 304l stainless steel pipe clamps in direct use. Stresscorrosion cracking of a monel 400 tube springerlink. Most pitting corrosion in stainless alloys occurs in neutraltoacid solutions with chloride or ions containing chlorine. The tomography scans showed the crack morphology evolving into a.
Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Type 304, with its chromiumnickel content and low carbon, is the most versatile and widely used of the austenitic stainless steels. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. Chloride induced stress corrosion cracking of type 304 and 304l stainless steels in air article pdf available in zairyotokankyo 523. The amount of chlorine contamination for prevention of stress corrosion cracking in sensitized type 304 stainless steel moriyasu tokiwai, hideo kimura and hideo kusanagi central research institute of electric power industry, energy and environmental laboratory, 111. This study is to identify factors responsible for loss of production due to problems in plant and equipment.
To understand the mechanisms behind chlorine induced stress corrosion cracking ciscc in 304 stainless steel, synchrotron high energy xrays were used to perform in situ xray microtomography on a precracked sample under load in a corrosive simulated marine environment. Therefore, is one of the key parameters needed for prediction of initiation of reinforcement corrosion. This sim alerts inspectors to potential failures in swimming pool buildings due to stress corrosion cracking in stainless steels induced by the atmospheric conditions. To understand the mechanisms behind chlorineinduced stress corrosion cracking ciscc in 304 stainless steel, synchrotron high energy xrays were used to perform insitu xray microtomography on a precracked sample under load in a corrosive simulated marine environment. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. Guidelines for using stainless steel in the water and. The amount of chlorine contamination for prevention of stress. It destroys the passivation layer of stainless steel and causing pitting corrosion. It has been shown that h 2 s induced stress corrosion cracking attack is worst at temperatures around 80c 176f, but cracking can occur also at temperatures below 60c 140f.
Soilside chlorideinduced stress corrosion cracking under insulation a length of tp 304 stainless steel pipe in service as a high pressure steam condensate return in an outdoor underground environment beneath a sidewalk along a roadway suffered cracking near its welded ends, while the main body showed no visual signs of failure. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. The stress corrosion process is outlined and the susceptibility of grades 1. The pipeline was used to carry a stream of gaseous hydrocarbons containing hydrochloric acid hcl into a reaction tower. It has been shown that h 2 sinduced stress corrosion cracking attack is worst at temperatures around 80c 176f, but cracking can occur also at temperatures below 60c 140f. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Chloride stress corrosion cracking in austentic hse. The effect of salt loading on chlorideinduced stress corrosion cracking in 304 l was studied at atmospheric pressure.
Background 1 in 1985, 12 people were killed in uster, switzerland when the concrete roof of a swimming pool collapsed. Stress corrosion cracking of sensitized type 304 stainless steel in high temperature chloride solutions. Pdf chloride induced stress corrosion cracking of type 304 and. Chloride induced stress corrosion cracking of type 304 and. Chlorides simulating sea salt particles were put on the gage section of.
Type 316 is an austenitic chromiumnickel stainless and heatresisting steel with superior corrosion resistance as compared to other chromiumnickel steels when exposed to. In many alloy systems, scc is also associated to specific potential win. Scc propagation rates for atmospheric corrosion of 304ss. The effect of salt loading on chlorideinduced stress corrosion cracking of 304l austenitic stainless steel under atmospheric conditions. The effect of salt loading on chlorideinduced stress corrosion. The federal materials testing institute, based in duebendorf, switzerland, and the federal materials research and testing institute of berlin concluded that the collapse was the result of chlorideinduced stress corrosion cracking. Chloride stress corrosion cracking in austenitic stainless. A bent nicu monel 400 alloy tube, which operated as part of a pipeline in a petrochemical distillery installation, failed by throughthickness cracking. Soilside chlorideinduced stress corrosion cracking under. It also offers high resistance to chlorineinduced stress corrosion cracking. A dissertation submitted to the university of london. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Stress corrosion cracking scc is a term used to describe service failure in engineering materials that occur by slow environmentally induced crack propagation1.
Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Summary of available data for estimating chlorideinduced scc. Ficks second law of diffusion has been used for long time to derive the models for chloride diffusion in. Highly alloyed austenitic stainless steels s32654, s31254, and n08028, and duplex grades s32750 and s31803 possess much improved resistance to. Chloride induced stress corrosion cracking scc is one of the failure modes of stainless steels. Simulated sea salt was deposited on the surface of the samples, using a salt fog procedure. Mechanism of chloride stress corrosion cracking of. Understanding the risk of chloride induced stress corrosion. Initiation of corrosion of steel in reinforced concrete rc structures subjected to chloride exposures mainly depends on coefficient of chloride diffusion, of concrete. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Pdf chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in. Stress relieved samples were uniaxially prestrained to 5% and were loaded with nine levels of mgcl 2, investigating cl.